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Systematic analysis of the high temperature resistance of aerogel
2025-12-31       Source:

In the fields of industrial equipment, energy systems, and high-temperature pipeline insulation, insulation materials not only need to possess low thermal conductivity but also maintain structural and performance stability under high-temperature environments. Aerogel, as a novel porous insulation material, has its high-temperature resistance performance becoming a crucial consideration in engineering selection. This article will systematically analyze the high-temperature resistance performance of aerogel from the perspectives of material structure, temperature resistance mechanism, and engineering applications.


I. Basic Requirements for Insulation Materials under High-Temperature Conditions


In high-temperature operating environments, insulation materials must simultaneously meet the following requirements:


No significant structural damage at high temperatures


Controllable changes in insulation performance with increasing temperature


No significant melting, collapse, or failure phenomena


Ability to adapt to long-term thermal cycling conditions


Aerogel is applied to some high-temperature insulation scenarios precisely because of these requirements.


II. Material Composition and High-Temperature Resistance Basis of Aerogels


Aerogels commonly used in engineering applications are mostly inorganic aerogel systems, characterized by:


A primary framework of inorganic materials such as silica


A nano-network structure formed through a sol-gel process


High internal porosity and extremely small pore size


This inorganic framework structure is a crucial foundation for the high-temperature resistance of aerogels.


III. Formation Mechanism of High-Temperature Resistance of Aerogels


1. High-Temperature Stability of the Inorganic Framework Structure


The three-dimensional nano-framework within aerogels:


Refuses to melt at high temperatures


Maintains basic morphological stability


Strong resistance to thermal decomposition


This allows it to maintain its thermal insulation function even in high-temperature environments.


2. Nanoporous Structure Inhibits Heat Conduction


Aerogel pore sizes are typically in the nanometer range:


Gas molecule movement is restricted


Heat convection is almost entirely suppressed


The heat conduction process is mainly solid-to-solid conduction with extremely long paths


This structural characteristic persists even under high-temperature conditions.


3. Control of Radiative Heat Transfer at High Temperatures


As temperature increases, the proportion of radiative heat transfer increases. Aerogels typically reduce the impact of high-temperature radiation on overall thermal conductivity through:


Composite fiber reinforced structures


Surface coatings or the addition of heat-shielding components


IV. Performance of Aerogels in High-Temperature Environments


From an engineering practice perspective, aerogels typically exhibit the following characteristics in high-temperature conditions:


Their thermal insulation performance changes gradually with increasing temperature


Their structure remains stable within the specified temperature range


They are not prone to significant shrinkage or powdering


Therefore, aerogels can be used stably for extended periods in some medium- and high-temperature insulation applications.


V. Key Factors Affecting the High-Temperature Resistance of Aerogels


1. Aerogel Type and Formulation System


Different inorganic systems have different upper limits for temperature resistance.


Composite-reinforced aerogels exhibit more stable temperature resistance.


2. Fiber Reinforcement and Composite Structure Design


Single aerogels are relatively brittle.


Fiber reinforcement can improve high-temperature stability and mechanical strength.


3. Operating Environment and Temperature Fluctuations


Long-term high temperatures


Frequent thermal cycling


These factors all affect the service life of aerogels.


VI. Application Scenarios of Aerogel High-Temperature Resistance in Engineering


1. Industrial Pipeline and Equipment Insulation


Steam Pipelines


High-Temperature Process Pipelines


Energy System Equipment


2. Petrochemical and Energy Fields


External insulation for high-temperature reaction units


Areas with high heat loss control requirements


3. Situations with Strict Space Thickness Requirements


Compact equipment areas


Locations where the thickness of traditional insulation materials is limited.


The high-temperature resistance of aerogels stems from their inorganic nano-framework structure and high porosity.


Under reasonable temperature resistance and standardized engineering application conditions, aerogels can continuously perform thermal insulation in high-temperature environments, providing an effective solution for heat loss control in industrial systems.